Construction of Improved HT-PEM MEAs and Stacks for Long Term Stable Modular CHP Units

CISTEM
Project Information
Framework Programme: 
FP7
Call for proposals: 
2012
Application area: 
Stationary power production and CHP
Logo: 

The vision of the CISTEM project is to develop a new fuel cell (FC) based CHP technology, which is suitable for fitting into large scale peak shaving  systems in relation to wind mills, natural gas and SMART grid applications. The technology should be integrated with localized power/heat production in order to utilize the heat from the FC via district heating and should deliver an electrical output of up to 100kW. Additionally the CHP system should be fuel flexible by use of natural gas or use of hydrogen and oxygen which can be provided by electrolysis. This gives the additional opportunity to store electrical energy in case of net overproduction by production of hydrogen and oxygen for use in the CHP system and gives an additional performance boost for the fuel cell.

The main idea of the project is a combined development of fuel cell technology and CHP system design. This gives the opportunity to develop an ideal new fuel cell technology for the special requirements of a CHP system in relation to efficiency, costs and lifetime. On the other hand the CHP system development can take into account the special advantages and disadvantages of the new fuel cell technology to realize an optimal system design.

The purpose of the CISTEM project is to show a proof of concept of high temperature PEM (HT-PEM) MEA technology for large combined heat and power (CHP) systems. A CHP system of 100 kWel will be set up and demonstrated. These CHP system size is suitable for district heat and power supply. The system will be build up modularly, with FC units of each 5 kWel output. This strategy of numbering up will achieve an optimal adaption of the CHP system size to a very wide area of applications, e.g. different building sizes or demands for peak shaving application.

Within CISTEM at least two 5 kWel modules will be implemented as hardware; the remaining 18 modules will be implemented as emulated modules in a hardware in the loop (HIL) test bench. The advantages of the 5 kW modular units are: suitable for mass production at lower production costs, higher system efficiency due to optimized operation of each unit, maintenance “on the run”, stability and reliability of the whole system. With the help of the HIL approach different climate conditions representing the European-wide load profiles can be emulated in detail. Furthermore, interfaces to smart grid application will be prepared.

Increased electrical efficiency for the FC will be obtained by the utilization of oxygen from the electrolyser which is normally wasted, as well as by general improvement of the FCs. Besides, the overall energy efficiency will also be improved by utilization of the produced heat in the district heating system. The latter is facilitated by high working temperature of the HT-PEM FC (i.e. 140 - 180˚C).

Project details
Project reference: 
325262
Topic: 
SP1-JTI-FCH.2012.3.1 - Cell and stack degradation mechanisms and methods to achieve cost reduction and lifetime enhancements SP1-JTI-FCH.2012.3.5 and System level proof of concept for stationary power and CHP fuel cell systems at a representative scale
Contract type: 
Collaborative Project
Start date: 
Saturday, June 1, 2013
End date: 
Friday, September 30, 2016
Duration: 
36 months (originally), extended to 40 months
Project cost: 
€ 6,097,180
Project funding: 
€ 3,989,723
Coordinator: 

EWE-Forschungszentrum für Energietechnologie e.v., Germany

Contact: 
Mr. Peter Wagner
Other participating organisations: 
Organisation Country
DANISH POWER SYSTEM APS Denmark
INHOUSE ENGINEERING GMBH Germany
Eisenhuth GmbH & Co. KG Germany
UNIVERSIDAD DE CASTILLA - LA MANCHA Spain
VYSOKA SKOLA CHEMICKO-TECHNOLOGICKA V PRAZE Czech Republic
ICI CALDAIE SPA Italy
OWI Oel-Waerme Institut GmbH Germany
Patents and Publications
Publications: 
Justo Lobato , Hector Zamora , Jorge Plaza , Manuel A. Rodrigo; Composite Titanium Silicon Carbide as a Promising Catalyst Support for High-Temperature Proton-Exchange Membrane Fuel Cell Electrodes
E. Pohl, M. Maximini, A. Bauschulte, J. vom Schloß, R.T.E. Hermanns; Degradation modeling of high temperature proton exchange membrane fuel cells using dual time scale simulation
Diego Úbeda , Pablo Cañizares , Manuel A. Rodrigo , F. Javier Pinar , Justo Lobato; Durability study of HTPEMFC through current distribution measurements and the application of a model
F. J. Pinar , M. Rastedt , N. Pilinski , P. Wagner; Effect of Compression Cycling on Polybenzimidazole-based High-Temperature Polymer Electrolyte Membrane Fuel Cells
F. Javier Pinar , Maren Rastedt , Nadine Pilinski , Peter Wagner; Effect of idling temperature on high temperature polymer electrolyte membrane fuel cell degradation under simulated start/stop cycling conditions
M. Rastedt , F. J. Pinar , N. Pilinski , A. Dyck , P. Wagner; Effect of Operation Strategies on Phosphoric Acid Loss in HT-PEM Fuel Cells
M. Rastedt , F. J. Pinar , N. Pilinski , P. Wagner; Effects of Reactant Gases on HT-PEM Fuel Cells
Araceli González del Campo, Francisco J. Fernández, Pablo Cañizares, Manuel A. Rodrigo, F. Javier Pinar, Justo Lobato; Energy recovery of biogas from juice waste water through a short high temperature PEMFC stack
Justo Lobato , Hector Zamora , Jorge Plaza , Pablo Cañizares , Manuel A. Rodrigo; Enhancement of high temperature PEMFC stability using catalysts based on Pt supported on SiC based materials
M. Rastedt , D. Schonvogel , P. Wagner; Impact of Load Cycling at High Current Densities on the Degradation Behavior of Membrane-Electrode-Assemblies
Héctor Zamora , Jorge Plaza , Pablo Cañizares , Justo Lobato , Manuel A. Rodrigo; Improved Electrodes for High Temperature Proton Exchange Membrane Fuel Cells using Carbon Nanospheres
H. Zamora, P. Canizares, M. A. Rodrigo, J. Lobato; Improving of Micro Porous Layer based on Advanced Carbon Materials for High Temperature Proton Exchange Membrane Fuel Cell Electrodes
N. Pilinski , M. Rastedt , P. Wagner; Investigation of Phosphoric Acid Distribution in PBI Based HT-PEM Fuel Cells
R. Kerr , H.R. García , M. Rastedt , P. Wagner , S.M. Alfaro , M.T. Romero , C. Terkelsen , T. Steenberg , H.A. Hjuler; Lifetime and degradation of high temperature PEM membrane electrode assemblies
Francisco Javier Pinar Pérez, Nadine Pilinski, Peter Wagner; Long-term Testing of a High Temperature Polymer Electrolyte Membrane Fuel Cell: The Effect of Reactant Gases
F. Javier Pinar, Pablo Cañizares, Manuel A. Rodrigo, Diego Úbeda, Justo Lobato; Long-term test of a High Temperature Proton Exchange Membrane Fuel Cell short Stack operated with improved Polybenzimidazole based composite membranes
M. Rastedt , F. J. Pinar , N. Bruns , A. Diedrichs , P. Wagner; Micro-Computed Tomography Imaging of HT-PEM Fuel Cells under Contact Pressure Control
Justo Lobato, Hector Zamora, Pablo Canizares, Jorge Plaza, Manuel Andrés Rodrigo; Microporous layer based on SiC for high temperature proton exchange membrane fuel cells
Roman Kodým , Monika Drakselová , Petr Pánek , Michal Němeček , Dalimil Šnita , Karel Bouzek; Novel approach to mathematical modeling of the complex electrochemical systems with multiple phase interfaces
F. Javier Pinar , Nadine Pilinski , Maren Rastedt , Peter Wagner; Performance of a high-temperature PEM fuel cell operated with oxygen enriched cathode air and hydrogen from synthetic reformate
Elmar Pohl , Pascal Meier , Marius Maximini , Jörg vom Schloß; Primary energy savings of a modular combined heat and power plant based on high temperature proton exchange membrane fuel cells
H. Akbari Khorami , N. Jacobs , P. Wagner , A. Dyck , P. Wild , N. Djilali; Stability of Prussian Blue Films for Sensing H2O2 in a PEM-fuel Cell Environment
M. Rastedt , F. J. Pinar , P. Wagner , H. R. Garcia , T. Steenberg , H. A. Hjuler , M. Paidar , K. Bouzek; Ultralow Degradation Rates in HT-PEM Fuel Cells
Diego Úbeda1, Justo Lobato1, Pablo Cañizares1, Francisco J. Pinar2, Hector Zamora1, Carmen M. Fernández-Marchante1, Manuel A. Rodrigo11 UCLM2 NEXT; Using Current Distribution Measurements to Characterize the Behaviour of HTPEMFCs
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